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008190130s1959    onc     ot   f|0| 0 eng d
040 |aCaOODSP|beng|erda|cCaOODSP
043 |an-cn---
0861 |aM38-1/52-1959E-PDF
1001 |aFlengas, S. N., |eauthor.
24510|aElectromotive force series of metals in fused salts and activities of metal chlorides in 1:1 molar KCl-NaCl solutions / |cby S. N. Flengas and T. R. Ingraham.
264 1|aOttawa, Ontario : |bDepartment of Mines and Technical Surveys, |c1959.
300 |a1 online resource (10 pages)
336 |atext|btxt|2rdacontent
337 |acomputer|bc|2rdamedia
338 |aonline resource|bcr|2rdacarrier
4901 |aMines Branch Research Report ; |vR 52
500 |a"Reprinted from Journal of the Electrochemical Society, Vol. 106, No. 8."
500 |a"August 1959."
504 |aIncludes bibliographic references.
520 |a"The potentials of a series of metal-metal chloride systems in an equimolar mixture of molten potassium and sodium chlorides have been measured against a silver-silver chloride reference electrode. An electromotive force series of metals at different temperatures has been established for this particular solvent. Experiments with a chlorine electrode have shown that the solutions of silver chloride in the KCl-NaCl solvent are ideal, and hence, deviations from ideality of the other chlorides in this solvent can be attributed directly to the formation of complexes in the rnelts. Three types of behavior have been observed for the salts studied in this solvent: ideality, and positive and negative deviations from ideality. The theoretical aspects of complex formation in melts are discussed"--Abstract.
69207|2gccst|aMetals
69207|2gccst|aChemicals
7001 |aIngraham, Thomas R., |eauthor.
7101 |aCanada. |bDepartment of Mines and Technical Surveys.
7101 |aCanada. |bMines Branch.
830#0|aResearch report (Canada. Mines Branch)|vR 52.|w(CaOODSP)9.855660
85640|qPDF|s3.65 MB|uhttps://publications.gc.ca/collections/collection_2019/rncan-nrcan/m38-1/M38-1-52-1959-eng.pdf