00000000nam 2200000zi 4500
0019.871735
003CaOODSP
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008190417s1996    onca   #ob   f000 0 eng d
040 |aCaOODSP|beng|erda|cCaOODSP
0861 |aEn13-5/96-83E-PDF
1001 |aLesage, Suzanne, |eauthor.
24510|aIdentification of alkylcobalamin intermediates in the reductive dechlorination of chlorinated ethenes by electrospray LC/MS / |cSuzanne Lesage, Susan Brown and Kelly Millar.
24614|aIdentification of alkylocbalamin intermediates in the reductive dechlorination of chlorinated ethenes by electrospray LC/MS
264 1|aBurlington, Ontario : |bEnvironment Canada, Water Science and Technology Directorate = Environnement Canada, Direction générale des sciences et de la technologie, eau, |c[1996?]
300 |a1 online resource (11 pages) : |billustrations.
336 |atext|btxt|2rdacontent
337 |acomputer|bc|2rdamedia
338 |aonline resource|bcr|2rdacarrier
4901 |aNWRI contribution ; |v96-83
500 |aTitle from caption.
500 |aDigitized edition from print [produced by Environment and Climate Change Canada].
504 |aIncludes bibliographical references.
520 |a"Several chloroalkyl intermediates formed during the reaction between tetrachloroethylene and aquocobalamin were identified by direct liquid injection in an Electrospray LC/MS. The concurrent presence of all reaction intermediates when combined with information on the dechlorination products formation, lead to a revised scheme on the possible pathways of the reductive dechlorination reaction catalysed by cobalamins (such as vitamin B 12). The new proposed pathways involve reductive dechlorination occurring on the alkyl cobalamins, and homolytic cleavage and titanium catalysed elimination as competing mechanisms for the formation of the products from the alkylcobalamin intermediates"--Abstract.
69207|2gccst|aWater management
69207|2gccst|aGroundwater
69207|2gccst|aPollutants
7001 |aBrown, Susan, |eauthor.
7001 |aMillar, K. R., |eauthor.
7101 |aCanada. |bEnvironment Canada.
7101 |aCanada. |bWater Science and Technology Directorate.
830#0|aNWRI contribution ;|v96-83.|w(CaOODSP)9.844121
85640|qPDF|s1.33 MB|uhttps://publications.gc.ca/collections/collection_2019/eccc/en13-5/En13-5-96-83-eng.pdf