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040 |aCaOODSP|beng|erda|cCaOODSP
041 |aeng|bfre
043 |an-cn---
0861 |aEn13-5/88-63E-PDF
1001 |aOnuska, Francis I., |d1935- |eauthor.
24510|aSupercritical fluid chromatography of alkylene oxide : |bfatty alcohol condensates : their quantitation in water samples / |cby Francis I. Onuska and K.A. Terry.
24610|aFatty alcohol condensates : |btheir quantitation in water samples
264 1|aBurlington, Ontario : |bNational Water Research Institute, Research and Applications Branch, Canada Centre for Inland Waters, |cFebruary 1988.
300 |a1 online resource (18 unnumbered pages) : |bgraphs.
336 |atext|btxt|2rdacontent
337 |acomputer|bc|2rdamedia
338 |aonline resource|bcr|2rdacarrier
4901 |aNWRI contribution ; |v88-63
500 |aDigitized edition from print [produced by Environment and Climate Change Canada].
504 |aIncludes bibliographical references.
520 |a"A method is described for the quantitative determination of linear alkylene oxide - fatty alcohol condensates, nonionic surface active agents in water. Surface active agent is extracted from water samples with benzene. Surfactant is further extracted by salting out into chloroform. Capillary, supercritical fluid chromatography allows the separation and quantitative determination of oligometric constituents using carbon dioxide as a supercritical fluid. In this case, a fingerprint of the surfactant is obtained. Analysis time, however, is approximately 60 minutes. In the second case, the ether groups of ethylene oxide fatty alcohol condensates are cleaved by reaction with 50 percent hydrobromic acid in glacial acetic acid in sealed ampoules. The resulting alkyl bromides are extracted with carbon disulfide and chromatographed by both the supercritical fluid, capillary column chromatography (SFC) and high resolution open tubular column gas chromatography (OTC - HRGC). Results are in good agreement between these two techniques"--Summary.
546 |aIncludes summary and management perspective in English and French.
69207|2gccst|aWater management
693 4|aSupercritical fluid chromatography
693 4|aSurface active agents
7001 |aTerry, K. A., |eauthor.
7101 |aCanada. |bEnvironment Canada.
7102 |aNational Water Research Institute (Canada). |bResearch and Applications Branch.
7102 |aCanada Centre for Inland Waters.
830#0|aNWRI contribution ;|v88-63.|w(CaOODSP)9.844121
85640|qPDF|s1.84 MB|uhttps://publications.gc.ca/collections/collection_2019/eccc/en13-5/En13-5-88-63-eng.pdf