The structure of HCl doped silicon oxides and of the overlaying metallization / by M. Bouchard, W.A. Hartman and R.M. Kuley.: Co24-3/7-1298-1976E-PDF

"The addition of chlorine during processing improves the dielectric properties of silicon dioxide by reducing the concentration of mobile ions in the oxide. Since about 1973 the industry has adopted an optimum value of approximately 4 vol % HCl:O₂ because of possible detrimental effects at higher concentrations of chlorine. We have found quantitatively that at higher concentrations of chlorine (e.g. 10 vol % HCl:O₂ mixture) the oxide surface becomes irregular and the excess chlorine forms pockets within the oxide. This work characterizes these oxide defects and shows that their number, size and distribution are influenced by the chlorine concentrations, the processing sequence, the cooling rate following the oxidation, and the wafer orientation. The oxide defects also cause a local lifting of most metallizations and can cause pitting of aluminum. These reliability hazards can be avoided by careful choice of processing parameters"--Abstract, page 1.

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Publication information
Department/Agency Communications Research Centre (Canada), issuing body.
Title The structure of HCl doped silicon oxides and of the overlaying metallization / by M. Bouchard, W.A. Hartman and R.M. Kuley.
Series title CRC report ; no. 1298
Publication type Series - View Master Record
Language [English]
Other language editions [French]
Format Electronic
Electronic document
Note(s) Issued also in French under title: La structure des oxydes de silicium dopés au HCl et leur revêtement métallique.
"Space Technology Branch."
"October 1976."
Digitized edition from print [produced by Innovation, Science and Economic Development Canada].
Some pages rotated in this copy.
Includes bibliographical references (pages 22-23).
Issued also in print format.
Publishing information Ottawa : Communications Research Centre, 1976.
Author / Contributor Bouchard, M., author.
Description 1 online resource (iii, 25 pages) : illustrations.
Catalogue number
  • Co24-3/7-1298-1976E-PDF
Subject terms Metal oxide semiconductors.
Silicon -- Oxidation.
Silicon oxide.
Hydrogen chloride.
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